Characterization of ionized carbenes in the gas phase

被引：34

作者：

Flammang, R

Nguyen, MT

Bouchoux, G

Gerbaux, P

机构：

[1] Univ Mons, Organ Chem Lab, B-7000 Mons, Belgium

[2] Univ Louvain, Dept Chem, B-3001 Heverlee, Belgium

[3] Ecole Polytech, CNRS, UMR 7651, Lab Mecanismes React, F-91128 Palaiseau, France

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2000年 / 202卷 / 1-3期

关键词：

mass spectrometry; thermochemistry; carbenes; heterocyclic carbenes; vinylidenes;

D O I：

10.1016/S1387-3806(00)00288-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The generation of carbene radical cations (R-C-R.+) and related ions in the gas phase using various mass spectrometric techniques is critically reviewed. Their reactions as well as their thermochemical properties obtained either experimentally or from ab initio quantum chemical methods are also discussed. The review covers the literature published during the last 20 years and includes more than 120 papers. (Int J Mass Spectrom 202 (2000) A8-A25) (C) 2000 Elsevier Science B.V.

引用

页码：A8 / A26

页数：19

共 124 条

[1]

[Anonymous], 1994, Advances in Carbene Chemistry

[2]

[Anonymous], 1998, Advances in Carbene Chemistry

[3] Looking for stable carbenes: The difficulty in starting anew [J].