Characterization of ionized carbenes in the gas phase

被引：34

作者：

Flammang, R

Nguyen, MT

Bouchoux, G

Gerbaux, P

机构：

[1] Univ Mons, Organ Chem Lab, B-7000 Mons, Belgium

[2] Univ Louvain, Dept Chem, B-3001 Heverlee, Belgium

[3] Ecole Polytech, CNRS, UMR 7651, Lab Mecanismes React, F-91128 Palaiseau, France

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2000年 / 202卷 / 1-3期

关键词：

mass spectrometry; thermochemistry; carbenes; heterocyclic carbenes; vinylidenes;

D O I：

10.1016/S1387-3806(00)00288-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The generation of carbene radical cations (R-C-R.+) and related ions in the gas phase using various mass spectrometric techniques is critically reviewed. Their reactions as well as their thermochemical properties obtained either experimentally or from ab initio quantum chemical methods are also discussed. The review covers the literature published during the last 20 years and includes more than 120 papers. (Int J Mass Spectrom 202 (2000) A8-A25) (C) 2000 Elsevier Science B.V.

引用

收藏

页码：A8 / A26

页数：19

相关论文

共 124 条

[31] CALCULATIONS CONCERNING THE HCO+/HOC+ ABUNDANCE RATIO IN DENSE INTERSTELLAR CLOUDS [J].

DEFREES, DJ ;

MCLEAN, AD ;

HERBST, E .

ASTROPHYSICAL JOURNAL, 1984, 279 (01) :322-334

[32]

Duley W. W., 1984, INTERSTELLAR CHEM

[33] GASEOUS NEGATIVE-IONS FROM NEUTRAL MOLECULES AND POSITIVE-IONS - NEW INFORMATION FOR NEUTRALIZATION REIONIZATION MASS-SPECTROMETRY [J].

FENG, R ;

WESDEMIOTIS, C ;

MCLAFFERTY, FW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) :6521-6522

[34] THE DISTONIC HC+ (OH)OCH2 RADICAL CATION - A STABLE ISOMER OF IONIZED METHYL FORMATE [J].

FLAMMANG, R ;

PLISNIER, M ;

LEROY, G ;

SANA, M ;

NGUYEN, MT ;

VANQUICKENBORNE, LG .

CHEMICAL PHYSICS LETTERS, 1991, 186 (4-5) :393-400

[35] CHARACTERIZATION OF IMINOPROPADIENONE IONS AND NEUTRALS IN A TANDEM MASS-SPECTROMETER [J].

FLAMMANG, R ;

LAURENT, S ;

FLAMMANGBARBIEUX, M ;

WENTRUP, C .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1992, 6 (11) :667-670

[36] FORMATION AND IDENTIFICATION OF IONIZED AND NEUTRAL CUMULENES, RN=C=C=C=NH, BY TANDEM MASS-SPECTROMETRY [J].

FLAMMANG, R ;

LAURENT, S ;

FLAMMANGBARBIEUX, M ;

WENTRUP, C .

ORGANIC MASS SPECTROMETRY, 1993, 28 (10) :1161-1166

[37] Dehalogenation of protonated C-halogeno-1,2,4-triazoles:: synthesis of new heterocyclic carbenic and ylid radical cations and contrasting behaviour of collision gases [J].

Flammang, R ;

Barbieux-Flammang, M ;

Le, HT ;

Nguyen, MT ;

Berthelot, J ;

Tortajada, J .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2000, 199 (1-3) :221-233

[38]

Flammang R, 1996, RAPID COMMUN MASS SP, V10, P232, DOI 10.1002/(SICI)1097-0231(19960131)10:2<232::AID-RCM471>3.3.CO

[39]

2-4

[40] POLYCARBON SULFIDES CNS (N=2-6) AND CORRESPONDING HYDRIDES HCNS - NEUTRALIZATION-REIONIZATION MASS-SPECTROMETRY AND AB-INITIO MOLECULAR-ORBITAL STUDY [J].

FLAMMANG, R ;

VANHAVERBEKE, Y ;

WONG, MW ;

WENTRUP, C .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1995, 9 (03) :203-208

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