Polyaniline protonated with camphorsulfonic acid: modelling of its crystalline structure

被引：48

作者：

Luzny, W

Samuelsen, EJ

Djurado, D

Nicolau, YF

机构：

[1] STANISLAW STASZIC UNIV MIN & MET,FAC PHYS & NUCL TECH,PL-30059 KRAKOW,POLAND

[2] UNIV GRENOBLE 1,SPECTROMETRIE PHYS LAB,UMR 5588 CNRS,F-38402 ST MARTIN DHER,FRANCE

[3] CEN GRENOBLE,PMS,SI3M,DEPT RECH FONDAMENTALE MAT CONDENSEE,CEA,F-38054 GRENOBLE 9,FRANCE

来源：

SYNTHETIC METALS | 1997年 / 90卷 / 01期

关键词：

polyaniline and derivatives; camphorsulfonic acid; crystalline structures;

D O I：

10.1016/S0379-6779(97)03908-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polyaniline (PANI) (in the form of emeraldine) protonated with (+/-) camphorsulfonic acid (CSA) was subjected to computer modelling of its crystalline structure. Diffraction patterns were calculated for some modelled structures with the aim of obtaining the best agreement with observed X-ray diffraction patterns (recorded on films cast from m-cresol solutions) and with measured density. The model structures consist of layers of parallel PANI chains intercalated by CSA molecules, that do not contain nl-cresol. Two particular models are presented and their features are discussed. (C) 1997 Elsevier Science S.A.

引用

页码：19 / 23

页数：5

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