First examples of polymeric mixed-metal (Pt-Ag) complexes containing single acetamidate bridges: cis-[(NH3)(2)Pt(NHCOMe)(2)Ag]NO3 center dot 4H(2)O and trans-[(NH3)(2)Pt(NHCOMe)(2)Ag]NO3 center dot 1.5H(2)O

被引：37

作者：

Erxleben, A ^{[1
]}

Lippert, B ^{[1
]}

机构：

[1] UNIV DORTMUND,FACHBEREICH CHEM,D-44221 DORTMUND,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 11期

关键词：

D O I：

10.1039/dt9960002329

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of AgNO3 with trans- and cis-[Pt(NH3)(2)(NHCOMe-N)(2)] 1 and 2 yielded the heteronuclear polymeric complexes cis-[(NH3)(2)Pt(NHCOMe)(2)Ag]NO3 . 4H(2)O 3 and trans-[(NH3)(2)Pt(NHCOMe)(2)Ag]NO3 1.5H(2)O 4. Complexes 3 and 4 have been studied in solution and characterised by X-ray analysis: 3, tetragonal, space group I4(1)/a, a = b = 15.874(2), c = 22.918(5) Angstrom, Z = 16; 4, triclinic, space group P (1) over bar, a = 7.143(3), b = 8.416(5), c = 11.544(6) Angstrom, alpha = 78.61(4), beta = 89.67(4), gamma = 83.79(4)degrees, Z = 2. The Pt ... Ag distances are 2.897(1) and 2.903(1) (3) and 2.925(2) and 2.919(2) Angstrom (4). Possible metal-metal bonding interactions are discussed.

引用

页码：2329 / 2333

页数：5

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