Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly

被引：94

作者：

Eubank, Jarrod F.

Kravtsov, Victor Ch.

Eddaoudi, Mohamed

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Moldavian Acad Sci, Inst Phys Appl, MD-2028 Kishinev, Moldova

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 18期

关键词：

D O I：

10.1021/ja070924n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-ligand directed assembly of copper(II) ions and chelidonate (CDO) ligands into a metal-organic assembly has resulted in the proper orientation and positioning of CDO ligands for [2 + 2] photodimerization in the solid state. Upon exposure to ultraviolet light, pairs of adjacent CDO ligands photoreact via single-crystal-to-single-crystal cycloaddition to form novel cage dimers within the metal-organic assembly, which can be isolated successively as the organic sodium salt.

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页码：5820 / +

页数：3

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