Methyl, hydrochalcogenido, and phenylchalcogenolate complexes of zinc in a sulfur rich coordination environment:: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroboratozinc complexes [TmBut]ZnMe, [TmBut]ZnEH (E = S, Se) and [TmBut]ZnEPh (E = O, S, Se, Te)

被引：46

作者：

Melnick, JG ^{[1
]}

Docrat, A ^{[1
]}

Parkin, G ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 24期

关键词：

D O I：

10.1039/b412218f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of hydrochalcogenido and phenylchalcogenolate complexes of zinc supported by tris(2-mercapto-1-tert-butylimidazolyl)hydroborato ligation, [Tm-But]ZnEH (E = S, Se) and [Tm-But]ZnEPh (E = O, S, Se, Te) have been synthesized from [Tm-But]ZnMe; structural characterization by X-ray diffraction indicates that the variation in Zn-E bonding as a function of the chalcogen is significantly different from that in other series of metal-chalcogenolate compounds.

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页码：2870 / 2871

页数：2

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