Preparation of hard mesoporous silica spheres

被引：358

作者：

Huo, QS

Feng, JL

Schuth, F

Stucky, GD

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

[2] UNIV CALIF SANTA BARBARA,CTR QUANTIZED ELECT STRUCT,SANTA BARBARA,CA 93106

[3] UNIV FRANKFURT,INST ANORGAN CHEM,D-60439 FRANKFURT,GERMANY

[4] UNIV CALIF SANTA BARBARA,DEPT MAT,SANTA BARBARA,CA 93106

来源：

CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 01期

关键词：

D O I：

10.1021/cm960464p

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Large, hard, transparent, mesoporous silica spheres are synthesized in one step by using oil-in-water emulsion chemistry under basic conditions with cationic surfactants and (n-BuO)(4)Si. The pores are shown by TEM and nitrogen absorption studies to be monodispersed in size, with total surface area over 1000 m(2)/g.

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页码：14 / &

页数：5

相关论文

共 24 条

[1] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[2]

BRECK DW, 1974, ZEOLITE MOL SIEVES, P749

[3]

FENELOV VA, 1983, PREPARATION CATALYST, V3, P665

[4] COOPERATIVE ORGANIZATION OF INORGANIC-SURFACTANT AND BIOMIMETIC ASSEMBLIES [J].

FIROUZI, A ;

KUMAR, D ;

BULL, LM ;

BESIER, T ;

SIEGER, P ;

HUO, Q ;

WALKER, SA ;

ZASADZINSKI, JA ;

GLINKA, C ;

NICOL, J ;

MARGOLESE, D ;

STUCKY, GD ;

CHMELKA, BF .

SCIENCE, 1995, 267 (5201) :1138-1143

[5] Surfactant control of phases in the synthesis of mesoporous silica-based materials [J].

Huo, QS ;

Margolese, DI ;

Stucky, GD .

CHEMISTRY OF MATERIALS, 1996, 8 (05) :1147-1160

[6]

Iler R.K., 1979, The Chemistry of Silica

[7] THE SCIENCE AND APPLICATIONS OF EMULSIONS - AN OVERVIEW [J].

ISRAELACHVILI, J .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1994, 91 :1-8

[8] SPHERICAL AND POROUS GRAIN OF SILICA GEL AS REACTION PRODUCT [J].

KOHLSCHUTTER, HW ;

MIHM, U .

KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE, 1971, 243 (02) :148-+

[9] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

[10]

KWANT GJ, 1994, CHEM ENG SCI, V49, P4299