Nanoscale molecular organometallo-wires containing diruthenium cores

被引：165

作者：

Wong, KT

Lehn, JM

Peng, SM

Lee, GH

机构：

[1] Univ Strasbourg 1, ISIS, F-67000 Strasbourg, France

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b005679k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A conjugated linear molecule 3 of nanometric size containing two diruthenium units as redox active linkers has been synthesised; its electrochemical properties indicate molecular wire-type delocalization.

引用

页码：2259 / 2260

页数：2

共 23 条

[1] MOLECULAR DEVICES - CAROVIOLOGENS AS AN APPROACH TO MOLECULAR WIRES SYNTHESIS AND INCORPORATION INTO VESICLE MEMBRANES [J].

ARRHENIUS, TS ;

BLANCHARDDESCE, M ;

DVOLAITZKY, M ;

LEHN, JM ;

MALTHETE, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1986, 83 (15) :5355-5359

[2] Effect of axial ligands on the oxidation state, structure, and electronic configuration of diruthenium complexes. Synthesis and characterization of Ru-2(dpf)(4)Cl, Ru-2(dpf)(4)(C CC6H5), Ru-2(dpf)4(C CC6H5)(2), and Ru-2(dpf)4(CN)(2) (dpf equals N,N'-diphenylformamidinate) [J].

Bear, JL ;

Han, BC ;

Huang, SR ;

Kadish, KM .

INORGANIC CHEMISTRY, 1996, 35 (10) :3012-3021

[3] Syntheses of metal diynyl complexes: Novel routes to all-carbon ligands [J].

Bruce, MI ;

Ke, MZ ;

Low, PJ .

CHEMICAL COMMUNICATIONS, 1996, (21) :2405-2406

[4] Oxidation chemistry of metal-bonded C4 chains:: A combined chemical, spectroelectrochemical, and computational study [J].

Bruce, MI ;

Low, PJ ;

Costuas, K ;

Halet, JF ;

Best, SP ;

Heath, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (09) :1949-1962

[5]

COLLBERT MCB, 1997, J CHEM SOC DA, P99

[6] SYNTHESIS OF METAL ACETYLIDES VIA PALLADIUM-CATALYZED CARBON METAL BOND FORMATION [J].

CRESCENZI, R ;

LOSTERZO, C .

ORGANOMETALLICS, 1992, 11 (12) :4301-4305

[7] Toward metal-capped one-dimensional carbon allotropes:: Wirelike C6-C20 polyynediyl chains that span two redox-active (η5-C5Me5)Re(NO)(PPh3) endgroups [J].

Dembinski, R ;

Bartik, T ;

Bartik, B ;

Jaeger, M ;

Gladysz, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) :810-822

[8] SYNTHESIS OF MONONUCLEAR, DINUCLEAR AND OLIGOMERIC RIGID-ROD ACETYLIDE COMPLEXES OF RHODIUM, AND THE MOLECULAR-STRUCTURE OF [RH(PME3)4(CC-PARA-C6H4-CC)RH(PME3)4] [J].

FYFE, HB ;

MLEKUZ, M ;

ZARGARIAN, D ;

TAYLOR, NJ ;

MARDER, TB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) :188-190

[9] A four-oxidation-state family of coordinated carbon:: The first isolable and crystallographically characterized triradical [M]-C4-[M]3+ [J].

Guillemot, M ;

Toupet, L ;

Lapinte, C .

ORGANOMETALLICS, 1998, 17 (10) :1928-1930

[10] OXIDATIVE COUPLING OF ACETYLENES [J].

HAY, AS .

JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (07) :1275-1276

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