3D porous metal-organic framework exhibiting selective adsorption of water over organic solvents

被引：144

作者：

Gu, Jin-Zhong

Lu, Wen-Guan

Jiang, Long

Zhou, Hong-Cai

Lu, Tong-Bu ^{[1
]}

机构：

[1] Sun Yat Sen Univ, MOE Key Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[3] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

[4] Lanzhou Univ, Sch Chem & Chem Engn, Lanzhou 730000, Peoples R China

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 15期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ic7004908

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D porous metal-organic framework (MOF) with 1D open channels has been constructed hydrothermally using Zn-II and a rigid planar ligand IDC3- (imidazole-4,5-dicarboxylate). This MOF can adsorb water selectively over organic solvents and can be regenerated and reused. It also represents a rare example of a MOF with open channels that form/collapse reversibly upon hydration/dehydration.

引用

页码：5835 / 5837

页数：3

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