Ferrocenyl-passivated nanoclusters:: Synthesis of [CU20Se6(Se2fc)4(PR2R′)10] and [CU40Se12(Se2fc)8(PPh3)9]

被引：28

作者：

Wallbank, AI

Borecki, A

Taylor, NJ

Corrigan, JF ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Waterloo, Waterloo, ON N2L 3G1, Canada

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 05期

关键词：

D O I：

10.1021/om049238c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reagent Fe(eta(5)-C5H4SeSiMe3)(2) has been used for the formation of the new nanoclusters [Cu20Se6(Se(2)fc)(4)(PR2R')(10)] (R = Ph, R' = Et; R = R' = nBu) and [Cu40Se12(Se(2)fc)(8)(PPh3)(9)], which consist of ferrocenyl-passluated surfaces on CuSe cores.

引用

页码：788 / 790

页数：3

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