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Very stable and highly regioselective supported ionic-liquid-phase (SILP) catalysis: Continuous flow fixed-bed hydroformylation of propene

被引：254
作者：
Riisager, A
Fehrmann, R
Flicker, S
van Hal, R
Haumann, M
Wasserscheid, P
机构：
[1] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby KGS, Denmark
[2] Tech Univ Denmark, Interdisciplinary Res Ctr Catalysis, ICAT, DK-2800 Lyngby KGS, Denmark
[3] Univ Erlangen Nurnberg, Lehrstuhl Chem Reaktionstech, D-91058 Erlangen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 05期
关键词：
catalyst development; hydroformylation; ionic liquids; phosphine ligands; rhodium;
D O I：
10.1002/anie.200461534
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The advantages of heterogeneous catalysis and transition-metal catalysis in ionic liquids are combined in rhodium bisphosphine catalysts in an ionic-liquid phase on a silica support. These active, regioselective, and highly stable catalysts were applied in a fixed-bed reactor for the continuous-flow gas-phase hydroformylation of propene.
引用
收藏
页码：815 / 819
页数：5
相关论文
共 37 条
[1]   Increasing yield and operating time of SLP-catalyst processes by flow reversal and instationary operation [J].
Beckmann, A ;
Keil, FJ .
CHEMICAL ENGINEERING SCIENCE, 2003, 58 (3-6) :841-847
[2]   Solid catalysts on the basis of supported ionic liquids and their use in hydroamination reactions [J].
Breitenlechner, S ;
Fleck, M ;
Müller, TE ;
Suppan, A .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (01) :175-179
[3]  
Cornils B., 1996, APPL HOMOGENEOUS CAT
[4]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[5]  
Dupont J, 2000, J BRAZIL CHEM SOC, V11, P337
[6]  
Goedheijt MS, 1998, J MOL CATAL A-CHEM, V134, P243
[7]   New developments in catalysis using ionic liquids [J].
Gordon, CM .
APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) :101-117
[8]   Immobilization of Pd(OAc)2 in ionic liquid on silica:: Application to sustainable Mizoroki-Heck reaction [J].
Hagiwara, H ;
Sugawara, Y ;
Isobe, K ;
Hoshi, T ;
Suzuki, T .
ORGANIC LETTERS, 2004, 6 (14) :2325-2328
[9]  
Holbrey JD., 1999, Clean. Prod. Process., V1, P223, DOI [10.1007/s100980050036, DOI 10.1007/S100980050036]
[10]   Pd nanoparticles immobilized on molecular sieves by ionic liquids: Heterogeneous catalysts for solvent-free hydrogenation [J].
Huang, J ;
Jiang, T ;
Gao, HX ;
Han, BX ;
Liu, ZM ;
Wu, WZ ;
Chang, YH ;
Zhao, GY .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (11) :1397-1399
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