Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs

被引：121

作者：

Alcarazo, Manuel ^{[1
]}

Gomez, Catherine

Holle, Sigrid

Goddard, Richard

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 33期

关键词：

boranes; carbodiphosphoranes; donor-acceptor systems; frustrated Lewis pairs; hydrogen activation; HETEROLYTIC DIHYDROGEN ACTIVATION; FREE CATALYTIC-HYDROGENATION; DIVALENT CARBON(0) CHEMISTRY; N-HETEROCYCLIC CARBENE; HEXAPHENYLCARBODIPHOSPHORANE; PHOSPHINES; COMPLEXES; MECHANISM; BORANE; CARBODICARBENE;

D O I：

10.1002/anie.201002119

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

chemical equation presented Twice frustrated: The unusual electronic distribution around the central carbon(0) atom in carbodiphosphoranes makes this center so basic that, even after a first alkylation step, it is still able to act as a cationic Lewis base in the framework of frustrated Lewis pair chemistry. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5788 / 5791

页数：4

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