Biocatalysis with enzymes immobilized on mesoporous hosts: the status quo and future trends

被引:297
作者
Hartmann, Martin [1 ]
Jung, Dirk [2 ]
机构
[1] Univ Erlangen Nurnberg, Erlangen Catalysis Resource Ctr, D-91058 Erlangen, Germany
[2] Univ Augsburg, D-80159 Augsburg, Germany
关键词
TRAMETES-VERSICOLOR LACCASE; IONIC LIQUID SOLVENT; PENICILLIN ACYLASE; ENHANCED ACTIVITY; SILICA MATERIALS; EFFICIENT; CHLOROPEROXIDASE; OXIDATION; LIPASE; RESOLUTION;
D O I
10.1039/b907869j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Biocatalysis opens the door to green and sustainable processes in synthetic chemistry, in the production of natural products, and in waste management. Furthermore, due to the often similar reaction conditions, biocatalysis is ideally suited for realization of multi-step reactions. The key to Successful process optimization. especially for industrial applications of enzyme-catalyzed reactions. is immobilization. Enzyme immobilization oil ordered mesoporous supports enhances their operational stability and enables the use of enzymes as reusable and robust biocatalysts even for continuous processes. In this feature article, the use of enzymes immobilized on mesoporous Supports in biocatalysis is reviewed and future trends are pointed out.
引用
收藏
页码:844 / 857
页数:14
相关论文
共 77 条
[11]   Pressure-driven enzyme entrapment in siliceous mesocellular foam [J].
Han, Y ;
Lee, SS ;
Ying, JY .
CHEMISTRY OF MATERIALS, 2006, 18 (03) :643-649
[12]   Ordered mesoporous materials for bioadsorption and biocatalysis [J].
Hartmann, M .
CHEMISTRY OF MATERIALS, 2005, 17 (18) :4577-4593
[13]   Selective oxidation of indole by chloroperoxidase immobilized on the mesoporous molecular sieve SBA-15 [J].
Hartmann, Martin ;
Streb, Carsten .
JOURNAL OF POROUS MATERIALS, 2006, 13 (3-4) :347-352
[14]  
He X, 2002, ANGEW CHEM INT EDIT, V41, P214, DOI 10.1002/1521-3773(20020118)41:2<214::AID-ANIE214>3.0.CO
[15]  
2-D
[16]   Immobilization of cytochrome P-450 on MCM-41 with different silicon/aluminum ratios [J].
Hernández, MCR ;
Wejebe, JEM ;
Alcántara, JIV ;
Ruvalcaba, RM ;
Serrano, LAG ;
Ferrara, JT .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 80 (1-3) :25-31
[17]   Continuous kinetic resolution catalysed by cross-linked enzyme aggregates, 'CLEAs', in supercritical CO2 [J].
Hobbs, Helen R. ;
Kondor, Betti ;
Stephenson, Phil ;
Sheldon, Roger A. ;
Thomas, Neil R. ;
Poliakoff, Martyn .
GREEN CHEMISTRY, 2006, 8 (09) :816-821
[18]   Lipases and their industrial applications - An overview [J].
Houde, A ;
Kademi, A ;
Leblanc, D .
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 2004, 118 (1-3) :155-170
[19]   Comparative study of immobilized Trametes versicolor laccase on nanoparticles and kaolinite [J].
Hu, Xiaoke ;
Zhao, Xueheng ;
Hwang, Huey-min .
CHEMOSPHERE, 2007, 66 (09) :1618-1626
[20]   Proteins in Mesoporous Silicates [J].
Hudson, Sarah ;
Cooney, Jakki ;
Magner, Edmond .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (45) :8582-8594