A new feature in the chemistry of nitrobenzofuroxans:: ambident reactivity in Diels-Alder condensations

被引：38

作者：

Vichard, D

Hallé, JC

Huguet, B

Pouet, MJ

Riou, D

Terrier, F

机构：

[1] Univ Versailles, CNRS EP 102, Lab SIRCOB, F-78035 Versailles, France

[2] Univ Versailles, CNRS CO173, Lab IREM, F-78035 Versailles, France

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a800343b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 4,6-dinitrobenzofuroxan (DNBF) structure is shown to act both as a dienophile and a heterodiene upon treatment with 1-trimethylsilyloxybuta-1,3-diene and vinyl ethyl ether, providing in two steps a highly functionalised stereoselective compound.

引用

页码：791 / 792

页数：2

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