Glycosides of 2-C-methyl-D-erythritol from the fruits of anise, coriander and cumin

被引：26

作者：

Kitajima, J ^{[1
]}

Ishikawa, T ^{[1
]}

Fujimatu, E ^{[1
]}

Kondho, K ^{[1
]}

Takayanagi, T ^{[1
]}

机构：

[1] Showa Pharmaceut Univ, Tokyo 1948543, Japan

来源：

PHYTOCHEMISTRY | 2003年 / 62卷 / 01期

关键词：

2-C-methyl-D-erythritol glycoside; Anise; Primpinella anisum L; Coriander; Coriandrum sativum L; Cumin; Cuminum cyminum L; Umbelliferae;

D O I：

10.1016/S0031-9422(02)00438-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Eight glycosides of 2-C-methyl-D-erythritol (1) were isolated from the fruit of anise, and their structures were clarified as 1-O-beta-D-glucopyranoside, 3-O-beta-D-glucopyranoside, 4-O-beta-D-glucopyranoside, 1-O-beta-D-fructofuranoside, 3-O-beta-D-fructofuranoside, 4-O-beta-D-fructofuranoside, 1-O-beta-D-(6-O-4-hydroxybenzoyl)-glucopyranoside and 1-O-beta-D-(6-O-4-methoxybenzoyl)-glucopyranoside of 2-C-methyl-D-erythritol (2-9), respectively. Furthermore, 2 and 4 were isolated from the fruit of coriander, and 2, 3 and 4 were isolated from the fruit of cumin. Though the phosphate of 1 was known to be one of the first precursors of isoprenoids in the non-mevalonate pathway, and 1 is considered to be a common constituent in Umbelliferous plants, the glycosides of 1 are found for the first time. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：115 / 120

页数：6

共 7 条

[1] Deuterium-labelled isotopomers of 2-C-methyl-D-erythritol as tools for the elucidation of the 2-C-methyl-D-erythritol 4-phosphate pathway for isoprenoid biosynthesis [J].