Zinc-coordination oligomers of phenanthrolinylporphyrins

被引：9

作者：

Phillips-McNaughton, K ^{[1
]}

Groves, JT ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 11期

关键词：

PORPHYRINS;

D O I：

10.1021/ol034244a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the synthesis of mono- and bisphenanthrolinylporphyrins 5-(9-carboxy-1,10-phenanthroline-2),15-(p-tolyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphyrin (MPPc) and 5,15-bis(9-carboxy-1,10-phenanthroline-2)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphyrin (BPPc), respectively. The formation of dimers and oligomers, with MPPc and BPPc, respectively, upon exposure to zinc acetate is described. Oligomerization of the porphyrins was monitored spectrophotometrically, and a kinetic study was performed to estimate the average oligomer chain length.

引用

页码：1829 / 1832

页数：4

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