Aggregation controlled proton tautomerization in salicylideneanilines

被引：115

作者：

Ogawa, K ^{[1
]}

Harada, J ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2003年 / 647卷 / 1-3期

关键词：

tautomerization; thermochromism; salicylideneaniline; aggregation; hydrogen bonding;

D O I：

10.1016/S0022-2860(02)00526-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton tautomerization of salicylideneanilines in the solid state and in solution is reviewed, mainly focusing on the zwitterionic character of the NH form and its stabilization in the solid state and in solution at low temperature. The essential role of aggregation of molecules in proton tautomerization is emphasized. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：211 / 216

页数：6

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