Structure and reactivity of [{Te(NMe(2))(2)}(infinity)]; Application to the preparation of metalloorganic tellurium(II) compounds

被引：29

作者：

Allan, RE

Gornitzka, H

Karcher, J

Paver, M

Rennie, MA

Russell, CA

Raithby, PR

Stalke, D

Steiner, A

Wright, DS

机构：

[1] UNIV CAMBRIDGE, CHEM LAB, CAMBRIDGE CB2 1EW, ENGLAND

[2] UNIV GOTTINGEN, INST ANORGAN CHEM, D-37077 GOTTINGEN, GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 08期

关键词：

D O I：

10.1039/DT9960001727

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Condensation of the highly reactive complex [{Te(NMe(2))(2)}(infinity)] 1, prepared by the reaction of TeCl4 and Li[NMe(2)] (1.4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh(3))(2) 2, formed by the reaction of 1 with Ph(3)CSH (1:2 equivalents), have been determined.

引用

页码：1727 / 1730

页数：4

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