Ammonia-Treated Ordered Mesoporous Carbons as Catalytic Materials for Oxygen Reduction Reaction

被引:331
作者
Wang, Xiqing [1 ]
Lee, Je Seung [1 ]
Zhu, Qing [1 ]
Liu, Jun [2 ]
Wang, Yong [2 ]
Dai, Sheng [1 ]
机构
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[2] Pacific NW Natl Lab, Richland, WA 99352 USA
关键词
ELECTROLYTE FUEL-CELLS; NITROGEN-CONTAINING CARBON; ACTIVE-SITES; SUPPORT; METAL; ELECTROCATALYST; SPECTROSCOPY; ENHANCEMENT; TEMPERATURE; DURABILITY;
D O I
10.1021/cm100139d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ammonia treatment of ordered mesoporous carbons at high temperature results in the formation of nitrogen-doped carbon materials that exhibit significant activity for oxygen reduction reaction in acidic media. The new material shows an onset potential of only 80 mV below that of a commercial Pt-based catalyst, but a better stability. © 2010 American Chemical Society.
引用
收藏
页码:2178 / 2180
页数:3
相关论文
共 41 条
  • [1] A class of non-precious metal composite catalysts for fuel cells
    Bashyam, Rajesh
    Zelenay, Piotr
    [J]. NATURE, 2006, 443 (7107) : 63 - 66
  • [2] A review of Fe-N/C and Co-N/C catalysts for the oxygen reduction reaction
    Bezerra, Cicero W. B.
    Zhang, Lei
    Lee, Kunchan
    Liu, Hansan
    Marques, Aldalea L. B.
    Marques, Edmar P.
    Wang, Haijiang
    Zhang, Jiujun
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (15) : 4937 - 4951
  • [3] Scientific aspects of polymer electrolyte fuel cell durability and degradation
    Borup, Rod
    Meyers, Jeremy
    Pivovar, Bryan
    Kim, Yu Seung
    Mukundan, Rangachary
    Garland, Nancy
    Myers, Deborah
    Wilson, Mahlon
    Garzon, Fernando
    Wood, David
    Zelenay, Piotr
    More, Karren
    Stroh, Ken
    Zawodzinski, Tom
    Boncella, James
    McGrath, James E.
    Inaba, Minoru
    Miyatake, Kenji
    Hori, Michio
    Ota, Kenichiro
    Ogumi, Zempachi
    Miyata, Seizo
    Nishikata, Atsushi
    Siroma, Zyun
    Uchimoto, Yoshiharu
    Yasuda, Kazuaki
    Kimijima, Ken-ichi
    Iwashita, Norio
    [J]. CHEMICAL REVIEWS, 2007, 107 (10) : 3904 - 3951
  • [4] Synthesis and characterization of mesoporous carbon for fuel cell applications
    Chang, Hyuk
    Joo, Sang Hoon
    Pak, Chanho
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3078 - 3088
  • [5] Fe/N/C non-precious catalysts for PEM fuel cells: Influence of the structural parameters of pristine commercial carbon blacks on their activity for oxygen reduction
    Charreteur, Fanny
    Jaouen, Frederic
    Ruggeri, Stephane
    Dodelet, Jean-Pol
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (06) : 2925 - 2938
  • [6] Carbon-titania composite substrates for fuel cell catalyst applications
    Donthu, Suresh
    Cai, Mei
    Ruthkosky, Marty
    Halalay, Ion
    [J]. CHEMICAL COMMUNICATIONS, 2009, (28) : 4203 - 4205
  • [7] Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
    Gong, Kuanping
    Du, Feng
    Xia, Zhenhai
    Durstock, Michael
    Dai, Liming
    [J]. SCIENCE, 2009, 323 (5915) : 760 - 764
  • [8] Carbon alloy catalysts: Active sites for oxygen reduction reaction
    Ikeda, Takashi
    Boero, Mauro
    Huang, Sheng-Feng
    Terakura, Kiyoyuki
    Oshima, Masaharu
    Ozaki, Jun-ichi
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (38) : 14706 - 14709
  • [9] Heat-treated Fe/N/C catalysts for O2 electroreduction:: Are active sites hosted in micropores?
    Jaouen, F
    Lefèvre, M
    Dodelet, JP
    Cai, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (11) : 5553 - 5558
  • [10] Fe-based catalysts for oxygen reduction in PEMFCs - Importance of the disordered phase of the carbon support
    Jaouen, F
    Charreteur, F
    Dodelet, JP
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (04) : A689 - A698