A soluble donor-acceptor double-cable polymer: Polythiophene with pendant fullerenes

被引:25
作者
Cravino, A [1 ]
Zerza, G
Maggini, M
Bucella, S
Svensson, M
Andersson, MR
Neugebauer, H
Brabec, CJ
Sariciftci, NS
机构
[1] Johannes Kepler Univ Linz, LIOS Cells, A-4040 Linz, Austria
[2] Univ Padua, Dept Organ Chem, I-35131 Padua, Italy
[3] Chalmers Univ Technol, SE-41296 Gothenburg, Sweden
来源
MONATSHEFTE FUR CHEMIE | 2003年 / 134卷 / 04期
关键词
polythiophenes; fullerenes; double-cable polymers; photoinduced spectroscopy; organic photovoltaics;
D O I
10.1007/s00706-002-0555-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis and the spectroscopic properties of a novel soluble thiophene-based copolymer carrying pendant fullerene moieties (donor-acceptor double-cable polymer). Photoinduced absorption (PIA) experiments on spin cast films reveal a photoinduced electron transfer from the polythiophene chain onto the fullerene moieties. The performance of photovoltaic devices produced with this copolymer is also discussed.
引用
收藏
页码:519 / 527
页数:9
相关论文
共 22 条
[1]   The first ''charm bracelet'' conjugated polymer: An electroconducting polythiophene with covalently bound fullerene moieties [J].
Benincori, T ;
Brenna, E ;
Sannicolo, F ;
Trimarco, L ;
Zotti, G ;
Sozzani, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (06) :648-651
[2]   Influence of disorder on the photoinduced excitations in phenyl substituted polythiophenes [J].
Brabec, CJ ;
Winder, C ;
Scharber, MC ;
Sariciftci, NS ;
Hummelen, JC ;
Svensson, M ;
Andersson, MR .
JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (15) :7235-7244
[3]   Photovoltaic properties of conjugated polymer/methanofullerene composites embedded in a polystyrene matrix [J].
Brabec, CJ ;
Padinger, F ;
Sariciftci, NS ;
Hummelen, JC .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (09) :6866-6872
[4]  
Brabec CJ, 1998, AIP CONF PROC, V442, P519, DOI 10.1063/1.56441
[5]  
Cao LM, 2001, ADV MATER, V13, P1701, DOI 10.1002/1521-4095(200111)13:22<1701::AID-ADMA1701>3.0.CO
[6]  
2-Q
[7]   Electrochemical and photophysical properties of a novel polythiophene with pendant fulleropyrrolidine moieties: Toward "double cable" polymers for optoelectronic devices [J].
Cravino, A ;
Zerza, G ;
Neugebauer, H ;
Maggini, M ;
Bucella, S ;
Menna, E ;
Svensson, M ;
Andersson, MR ;
Brabec, CJ ;
Sariciftci, NS .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (01) :70-76
[8]   Double-cable polymers for fullerene based organic optoelectronic applications [J].
Cravino, A ;
Sariciftci, NS .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1931-1943
[9]   Grafting of buckminsterfullerene onto polythiophene: novel intramolecular donor-acceptor polymers [J].
Ferraris, JP ;
Yassar, A ;
Loveday, DC ;
Hmyene, M .
OPTICAL MATERIALS, 1998, 9 (1-4) :34-42
[10]   CONVENIENT SYNTHESIS OF VARIOUS TERHETEROCYCLIC COMPOUNDS BY PD(O)-CATALYZED COUPLING REACTIONS [J].
GRONOWITZ, S ;
PETERS, D .
HETEROCYCLES, 1990, 30 (01) :645-658