Electrical transport across a structurally ordered phthalocyanine film: Role of defect states

被引:5
作者
Boukari, S. [1 ]
Ghaddar, A. [1 ]
Henry, Y. [1 ]
Arabski, J. [1 ]
Da Costa, V. [1 ]
Bowen, M. [1 ]
Le Moigne, J. [1 ]
Beaurepaire, E. [1 ]
机构
[1] CNRS, ULP, IPCMS, UMR 7504, F-67034 Strasbourg 2, France
关键词
TUNNEL-JUNCTIONS; LARGE MAGNETORESISTANCE; CHARGE-TRANSPORT; TEMPERATURE; CONDUCTANCE; MOLECULES;
D O I
10.1103/PhysRevB.76.033302
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present transport measurements from 10 to 290 K on a junction made of metallic electrodes separated by a structurally ordered, 100 nm-thick metal-free H-2-phthalocyanine layer. Above 130 K, the junction is rectifying and the transport is thermally activated with a barrier of 0.148 eV. The conductance exhibits the signature of resonant tunneling across the energy levels of the molecules. Below 130 K, transport is activated with a barrier of 5.8x10(-4) eV and exhibits a zero-bias conductance anomaly at low temperature. We discuss these transport features, and the absence of magnetoresistance, in terms of the likely presence of defects due to the high structural quality of our organic spacer layer.
引用
收藏
页数:4
相关论文
共 24 条
[11]   Interface magnetism and spin wave scattering in ferromagnet-insulator-ferromagnet tunnel junctions [J].
Moodera, JS ;
Nowak, J ;
van de Veerdonk, RJM .
PHYSICAL REVIEW LETTERS, 1998, 80 (13) :2941-2944
[12]   LARGE MAGNETORESISTANCE AT ROOM-TEMPERATURE IN FERROMAGNETIC THIN-FILM TUNNEL-JUNCTIONS [J].
MOODERA, JS ;
KINDER, LR ;
WONG, TM ;
MESERVEY, R .
PHYSICAL REVIEW LETTERS, 1995, 74 (16) :3273-3276
[13]  
MULLER P, 2001, MAT PHYS MECH, V4, P76
[14]   Analytical model for molecular-scale charge transport [J].
Peterson, IR ;
Vuillaume, D ;
Metzger, RM .
JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (19) :4702-4707
[15]   Spin-dependent transport in molecular tunnel junctions [J].
Petta, JR ;
Slater, SK ;
Ralph, DC .
PHYSICAL REVIEW LETTERS, 2004, 93 (13) :136601-1
[16]  
ROCHA AR, PHYS REV B, V73
[17]   Room-temperature tunnel magnetoresistance and spin-polarized tunneling through an organic semiconductor barrier [J].
Santos, T. S. ;
Lee, J. S. ;
Migdal, P. ;
Lekshmi, I. C. ;
Satpati, B. ;
Moodera, J. S. .
PHYSICAL REVIEW LETTERS, 2007, 98 (01)
[18]   Temperature effects on conduction through a molecular junction [J].
Selzer, Y ;
Cabassi, MA ;
Mayer, TS ;
Allara, DL .
NANOTECHNOLOGY, 2004, 15 (07) :S483-S488
[19]   Theory of the zero-bias anomaly in magnetic tunnel junctions: Inelastic tunneling via impurities [J].
Sheng, L ;
Xing, DY ;
Sheng, DN .
PHYSICAL REVIEW B, 2004, 70 (09) :094416-1
[20]  
SIMON J, 1985, MOL ELECT SPRINGER V