Band structure measurement of organic single crystal with angle-resolved photoemission

被引:35
作者
Ding, Huanjun [1 ]
Reese, Colin [2 ]
Maekinen, Antti J.
Bao, Zhenan [2 ,3 ]
Gao, Yongli [1 ]
机构
[1] Univ Rochester, Dept Phys & Astron, Rochester, NY 14627 USA
[2] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[3] USN, Res Lab, Div Opt Sci, Washington, DC 20375 USA
关键词
Brillouin zones; organic semiconductors; photoelectron spectra; FIELD-EFFECT TRANSISTORS; CHARGE-TRANSPORT; RUBRENE;
D O I
10.1063/1.3446849
中图分类号
O59 [应用物理学];
学科分类号
摘要
The electronic structure of bulk rubrene single crystal was studied with angle-resolved photoemission spectroscopy. Highly reproducible dispersive features were observed with nice symmetry about the Brillouin zone center and boundaries, representing the band structure measured for a bulk organic single crystal. The high quality of the surface was confirmed with scanning tunneling microscopy. The energy dispersion of the highest occupied molecular orbitals derived bands showed strong anisotropic behavior in the a-b plane of the unit cell. The measured band structure, however, differs unexpectedly from theoretical calculations in terms of the amount of the dispersion and the separation of the bands. (C) 2010 American Institute of Physics. [doi:10.1063/1.3446849]
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页数:3
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