Synthesis of aza-heterocycles from oximes by amino-Heck reaction

被引：146

作者：

Kitamura, M ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMICAL RECORD | 2002年 / 2卷 / 04期

关键词：

amino-Heck reaction; aza-heterocycles; oxime; palladium;

D O I：

10.1002/tcr.10030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative addition of oximes to palladium(0) complexes generates alkylideneaminopalladium(II) species, which are utilized as key intermediates for carbon-nitrogen bond formation. Various aza-heterocycles, such as pyrrole, pyridine, isoquinoline, spiroimine, and azaazulene, can be synthesized from O-pentafluorobenzoyloximes having an olefinic moiety via an intramolecular Heck-type reaction (amino-Heck reaction) by treatment with a catalytic amount of a Pd(0) complex. (C) 2002 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.

引用

页码：268 / 277

页数：10

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