Role of network connectivity on the elastic, plastic and thermal behavior of covalent glasses

被引:19
作者
Feng, XW [1 ]
Bresser, WJ [1 ]
Zhang, M [1 ]
Goodman, B [1 ]
Boolchand, P [1 ]
机构
[1] Univ Cincinnati, Dept Elect & Comp Engn & Comp Sci, Cincinnati, OH 45221 USA
关键词
D O I
10.1016/S0022-3093(97)90106-X
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Experiments on chalcogenide glasses show that local elasticity as measured by Raman scattering and the kinetic heat-flow near T-g as established from temperature modulated differential scanning calorimetry each display a threshold behavior associated with network connectivity as defined by the mean coordination, [r], near [r] = [r](c) similar or equal to 2.40. Network plasticity of amorphous group IV networks as deduced from nanometer-indentation hardness measurements varies linearly with [r] once [r] > 2.40. Consequences of these results connecting physical behavior of covalent networks with their connectivity are discussed. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:137 / 143
页数:7
相关论文
共 29 条
[21]   CONFIGURATIONAL ARRANGEMENTS IN CHALCOGENIDE GLASSES - A NEW PERSPECTIVE ON PHILLIPS CONSTRAINT THEORY [J].
SENAPATI, U ;
VARSHNEYA, AK .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 185 (03) :289-296
[22]   ATOMIC CONSTRAINT IN HYDROGENATED DIAMOND-LIKE CARBON [J].
TAMOR, MA ;
VASSELL, WC ;
CARDUNER, KR .
APPLIED PHYSICS LETTERS, 1991, 58 (06) :592-594
[23]   FRAGILITY OF GE-AS-SE GLASS-FORMING LIQUIDS IN RELATION TO RIGIDITY PERCOLATION, AND THE KAUZMANN PARADOX [J].
TATSUMISAGO, M ;
HALFPAP, BL ;
GREEN, JL ;
LINDSAY, SM ;
ANGELL, CA .
PHYSICAL REVIEW LETTERS, 1990, 64 (13) :1549-1552
[24]  
THORPE MF, 1983, J NON-CRYST SOLIDS, V57, P355, DOI 10.1016/0022-3093(83)90424-6
[25]   Role of network topology on the vibrational lifetime of an H2O molecule in the Ge-As-Se glass series [J].
Uebbing, B ;
Sievert, AJ .
PHYSICAL REVIEW LETTERS, 1996, 76 (06) :932-935
[26]   STRUCTURE OF AMORPHOUS HYDROGENATED CARBON - EXPERIMENT AND COMPUTER-SIMULATION [J].
WEILER, M ;
KLEBER, R ;
SATTEL, S ;
JUNG, K ;
EHRHARDT, H ;
JUNGNICKEL, G ;
DEUTSCHMANN, S ;
STEPHAN, U ;
BLAUDECK, P ;
FRAUENHEIM, T .
DIAMOND AND RELATED MATERIALS, 1994, 3 (03) :245-253
[27]   MATHEMATICAL-DESCRIPTION OF DIFFERENTIAL SCANNING CALORIMETRY BASED ON PERIODIC TEMPERATURE MODULATION [J].
WUNDERLICH, B ;
JIN, YM ;
BOLLER, A .
THERMOCHIMICA ACTA, 1994, 238 :277-293
[28]   ONSET OF RIGIDITY IN SE1-XGEX GLASSES - ULTRASONIC ELASTIC-MODULI [J].
YUN, SS ;
LI, H ;
CAPPELLETTI, RL ;
ENZWEILER, RN ;
BOOLCHAND, P .
PHYSICAL REVIEW B, 1989, 39 (12) :8702-8706
[29]   THE CENTRAL ROLE OF BROKEN BOND-BENDING CONSTRAINTS IN PROMOTING GLASS-FORMATION IN THE OXIDES [J].
ZHANG, M ;
BOOLCHAND, P .
SCIENCE, 1994, 266 (5189) :1355-1357