Soluble Main-Chain Azobenzene Polymers via Thermal 1,3-Dipolar Cycloaddition: Preparation and Photoresponsive Behavior

被引：56

作者：

Xue, Xiaoqiang ^{[1
]}

Zhu, Jian ^{[1
]}

Zhang, Zhengbiao ^{[1
]}

Zhou, Nianchen ^{[1
]}

Tu, Yingfeng ^{[1
]}

Zhu, Xiulin ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

来源：

MACROMOLECULES | 2010年 / 43卷 / 06期

关键词：

SURFACE-RELIEF GRATINGS; NONLINEAR-OPTICAL POLYMERS; CLICK CHEMISTRY; HYPERBRANCHED POLYTRIAZOLES; PHOTOINDUCED BIREFRINGENCE; RAFT POLYMERIZATION; BLOCK-COPOLYMERS; AZO-POLYMERS; FILMS; CHROMOPHORE;

D O I：

10.1021/ma902671m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two soluble polymers containing azobenzene chromophore in main chain were successfully synthesized from alpha-azide, omega-alkyne A-B type azobenzene monomers, 3'-ethynylphenyl[4-hexoxyl(2-azido-2-inethylpropion<tte)phcnyl]azobenzene (EHPA) and 3'-etllytlylphenyl[4-(4-azidobutoxy)phenyl]azobellzene (EAPA), via thermal 1,3-dipolar cycloaddition in bulk, Compared to the polymers obtained from Cu(I)-catalyzed 1,3-dipolar cycloaddition ("click" chemistry), the polymers obtained from thermal 1,3-dipolar cycloaddition showed good solubility in common solvents like CHCl3 and THF and good film-forming ability. The polymers were thermally stable LIP to 330 degrees C. The structures of the main-chain azobenzene polymers were characterized by gel permeation chromatography (GPC), H-1 NMR, UV-vis, and FT-IR spectra. The photoinduced trans-cis isomerization of the polymers in chloroform (CHCl3) solution was examined. With illumination of linearly polarized Kr+ laser beam at 413.1 runt, surface relief gratings formed oil PEHPA2 spin-coating films were investigated.

引用

页码：2704 / 2712

页数：9

共 66 条

[61] Synthesis and properties of thermally cross-linkable main-chain azobenzene polymers containing diacetylene moieties [J].

Yu, Xiaowu ;

Luo, Yanhua ;

Deng, Yan ;

Yan, Qing ;

Zou, Gang ;

Zhang, Qijin .

EUROPEAN POLYMER JOURNAL, 2008, 44 (03) :881-888

[62] Synthesis of Amphiphilic ABC 3-Miktoarm Star Terpolymer by Combination of Ring-Opening Polymerization and "Click" Chemistry [J].

Yuan, You-Yong ;

Wang, Yu-Cai ;

Du, Jin-Zhi ;

Wang, Jun .

MACROMOLECULES, 2008, 41 (22) :8620-8625

[63] Convenient attachment of highly polar azo chromophore moieties to disubstituted polyacetylene through polymer reactions by using "Click" chemistry [J].

Zeng, Qi ;

Li, Zhong'an ;

Li, Zhen ;

Ye, Cheng ;

Qin, Jingui ;

Tang, Ben Zhong .

MACROMOLECULES, 2007, 40 (16) :5634-5637

[64] Synthesis and photoresponsive behaviors of well-defined azobenzene-containing polymers via RAFT polymerization [J].

Zhang, Yuanyuan ;

Cheng, Zhenping ;

Chen, Xinrong ;

Zhang, Wei ;

Wu, Jianhong ;

Zhu, Jian ;

Zhu, Xiulin .

MACROMOLECULES, 2007, 40 (14) :4809-4817

[65] Synthesis of double side-chain liquid crystalline block copolymers using RAFT polymerization and the orientational cooperative effect [J].

Zhao, Yi ;

Qi, Bo ;

Tong, Xia ;

Zhao, Yue .

MACROMOLECULES, 2008, 41 (11) :3823-3831

[66] Azobenzene-containing block copolymers: the interplay of light and morphology enables new functions [J].

Zhao, Yue ;

He, Jie .

SOFT MATTER, 2009, 5 (14) :2686-2693

← 1 2 3 4 5 6 7 →