Initiating and cross-linking ability of organic peroxides: Chemical kinetic methods for the determination

被引：3

作者：

Antonovskii, VL ^{[1
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia

来源：

KINETICS AND CATALYSIS | 2003年 / 44卷 / 01期

关键词：

Polymerization; Physical Chemistry; Peroxide; Hydroperoxide; Quantitative Determination;

D O I：

10.1023/A:1022568601041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review surveys chemical kinetic methods for the quantitative determination of the initiating C, and cross-linking ability of organic peroxides ROOR (peroxides, hydroperoxides, peroxyesters, diacyl peroxides, and peroxy carbonates). The conditions and limitations of the use of autoxidation, inhibitor, radical polymerization, and model cross-linking methods are analyzed. The results of the determination of the initiating and C cross-linking ability of the most important organic peroxides are cited.

引用

页码：54 / 73

页数：20

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