Mechanisms of excimer formation in poly(acenaphthylene)

被引：22

作者：

Chen, M

Ghiggino, KP ^{[1
]}

Smith, TA

Thang, SH

Wilson, GJ

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

[2] CSIRO Mol Sci, Clayton, Vic 3169, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2004年 / 57卷 / 12期

关键词：

D O I：

10.1071/CH04087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Excimer ( excited state dimer) formation mechanisms in solution have been investigated for a series of acenaphthyl-containing compounds comprising dimers, higher oligomers, and a poly( acenaphthylene) (PAcN) homopolymer. Excimer fluorescence is observed only for dimers with a threo-diisotactic arrangement of the acenaphthyl groups indicating that interactions between nearest-neighbour chromophores are able to play a role in excimer formation in PAcN. An increase in excimer emission is observed with increasing chain length and attributed to additional excimer formation and energy migration processes.

引用

页码：1175 / 1177

页数：3

共 9 条

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