[PtMe(iPr3P)2]+:: a Pt(II) complex with an agostic interaction that undergoes C-H activation

被引：72

作者：

Ingleson, MJ ^{[1
]}

Mahon, MF ^{[1
]}

Weller, AS ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 21期

关键词：

D O I：

10.1039/b410846a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].

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页码：2398 / 2399

页数：2

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