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Organotrifluoroborates: Protected boronic acids that expand the versatility of the Suzuki coupling reaction

被引：829
作者：
Molander, Gary A. [1 ]
Ellis, Noel [1 ]
机构：
[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2007年 / 40卷 / 04期
关键词：
D O I：
10.1021/ar050199q
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Organotrifluoroborates represent an alternative to boronic acids, boronate esters, and organoboranes for use in Suzuki-Miyaura and other transition-metal-catalyzed cross-coupling reactions. The trifluoroborate moiety is stable toward numerous reagents that are often problematic for other boron species. Consequently, remote functional groups within the organotrifluoroborates can be manipulated, while retaining the valuable carbon-boron bond.
引用
收藏
页码：275 / 286
页数：12
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