Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes

被引:11
作者
Abbotto, A
Beverina, L
Chirico, G
Facchetti, A
Ferruti, P
Gilberti, M
Pagani, GA
机构
[1] Univ Milano Bicocca, Dept Mat Sci, I-20125 Milan, Italy
[2] Univ Milano Bicocca, INSTM, I-20125 Milan, Italy
[3] Univ Milano Bicocca, INFM, I-20126 Milan, Italy
[4] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy
关键词
crosslinking; fluorescence; functionalization of polymers; NLO; UV-vis spectroscopy;
D O I
10.1002/marc.200390057
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amide-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high T-g thermoplastic polymers.
引用
收藏
页码:397 / 402
页数:6
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