Magnetic and gas-occlusion properties and catalytic activity of microporous materials: Dinuclear ruthenium(II,II) dicarboxylates

被引：23

作者：

Ohmura, T ^{[1
]}

Mori, W ^{[1
]}

Hiraga, H ^{[1
]}

Ono, M ^{[1
]}

Nishimoto, Y ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Sci, Dept Chem, Hiratsuka, Kanagawa 2591293, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 05期

关键词：

D O I：

10.1246/cl.2003.468

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new series of dinuclear ruthenium(II,II) dicarboxylates, but not dinuclear ruthenium(II,III) dicarboxylates, have been prepared. Dinuclear ruthenium(II,II) dicarboxylates, which have a regular two- or three-dimensional network structure, occlude large amounts of gas. The maximum amount of N-2 gas that can be occluded by these complexes is 1.0-1.7 moles per mole of ruthenium atoms, indicating the presence of a large number of micropores. These complexes exhibited pore volume-dependent catalytic activity for the hydrogenation of ethylene.

引用

页码：468 / 469

页数：2

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