Photodissociation dynamics of 13C16O excited by 193 nm light

被引：13

作者：

Bakker, BLG ^{[1
]}

Parker, DH ^{[1
]}

机构：

[1] Univ Nijmegen, Dept Mol & Laser Phys, NL-6525 ED Nijmegen, Netherlands

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 330卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(00)01122-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The two-photon dissociation dynamics of (CO)-C-13-O-16 is studied using a tunable ArF excimer laser and the velocity map imaging technique. C(D-1) atoms formed are detected via (1 + 1) resonance-enhanced multi-photon ionization (REMPI). The measured C(D-1) yield spectrum is assigned to the a(3)Pi(nu = 2) <-- X-1<Sigma>(+) (nu = 0) transition. Images containing velocity and angular distribution information are measured for the Q(1), R(0) and R(1) lines. The dissociation energy is confirmed to be 11.09 +/- 0.02 eV. Dissociation takes place after one-photon excitation of the a(3)Pi (1)(nu = 2) state via a Delta Omega = 0 (parallel) transition. A suggested dissociation process is predissociation of a(3)Pi (1) Rydberg state on a 16 +/- 5 ps time scale. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：293 / 299

页数：7

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