Synthesis and confirmation of structure for a new gibberellin, 2β-hydroxy-GA12(GA110), from spinach and oil palm

被引：9

作者：

Owen, DJ

Mander, LN ^{[1
]}

Storey, JMD

Huntley, RP

Gaskin, P

Lenton, JR

Gage, DA

Zeevaart, JAD

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0020, Australia

[2] Univ Cambridge, Dept Plant Sci, Cambridge CB2 3EA, England

[3] Univ Bristol, Long Ashton Res Stn, Dept Agr Sci, IACR, Bristol BS18 9AF, Avon, England

[4] Michigan State Univ, Dept Biochem, E Lansing, MI 48824 USA

[5] Michigan State Univ, Plant Res Lab, US DOE, E Lansing, MI 48824 USA

来源：

PHYTOCHEMISTRY | 1998年 / 47卷 / 03期

关键词：

Spinacia oleracea; chenopodiaceae; Elaeis guineesis; Palmae; spinach; oil palm; 2; beta-hydroxy-C-20-gibberellins; beta-hydroxy-GA(12); GA(110); beta-hydroxy-GA(24);

D O I：

10.1016/S0031-9422(97)00577-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The identity of a new gibberellin (GA) in spinach and oil palm sap has been confirmed as 2 beta-hydroxy-GA(12) (GA(110)) by comparisons of GC-mass spectral data obtained for the trimethylsilyl ether methyl ester derivatives with those of a synthetic sample prepared by means of a 24 step sequence from gibberellic acid; 2 beta-hydroxy-GA(24) was also prepared. Experimental details for the latter part of the syntheses are described. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：331 / 337

页数：7

共 16 条

[1] SYNTHESES OF C-20 GIBBERELLIN-A36 AND GIBBERELLIN-A37 METHYL-ESTERS FROM GIBBERELLIC-ACID [J].