Racemisation behaviour of trinuclear helicates formed from ethylene-bridged tris(catechol) ligands and titanium(IV) ions

被引:21
作者
Albrecht, M [1 ]
Schneider, M [1 ]
机构
[1] Univ Karlsruhe, Inst Organ Chem, D-76131 Karlsruhe, Germany
关键词
D O I
10.1039/a705663j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trinuclear helicates are self-assembled from ligand H6L1 and Ti-IV ions in the presence of sodium or potassium; carbonate and they racemise by consecutive inversion of the three complex units.
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页码:137 / 138
页数:2
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