Photoluminescence of 8-quinolinolato(trioxo) rhenium(VII)

被引：18

作者：

Kunkely, H ^{[1
]}

Vogler, A ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 11期

关键词：

rhenium complexes; luminescence;

D O I：

10.1016/S1387-7003(00)00149-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex (ReO3)-O-VII(oxinate) (oxine = 8-quinolinol or 8-hydroxyquinoline) shows a green fluorescence at lambda (max) = 511 nm with phi = 0.012 and a very weak red phosphorescence at lambda (max) = 645 nm. Both emissions originate from the lowest-energy pi pi* intraligand state of the oxinate ligand. Owing to the d(0) electron configuration and the high oxidation state of rhenium the heavy atom effect transmitted to the pi -electron system of the oxinate ligand is very weak. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：645 / 647

页数：3

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