Coherent picosecond vibron polaritons as probes of vibrational lifetimes

被引：13

作者：

Bonn, M ^{[1
]}

Woutersen, S ^{[1
]}

Bakker, HJ ^{[1
]}

机构：

[1] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands

来源：

OPTICS COMMUNICATIONS | 1998年 / 147卷 / 1-3期

关键词：

polarization; coherence; polariton; vibration; lifetime; infrared;

D O I：

10.1016/S0030-4018(97)00601-9

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Picosecond pump-probe experiments on the C-O stretch vibration of acetic acid in solution with infrared pulses from a free-electron laser are presented. We show that under typical experimental conditions of pulses that are short compared to the inverse absorption linewidth and optically thick samples (necessary to observe significant transmission changes), the experimental pump-probe data are strongly influenced by pulse propagation effects (vibron polaritons) and coherent coupling between pump and probe vibron polaritons. To extract the vibrational lifetime fi om the data, it is therefore necessary to perform a full simulation of the propagation and coupling effects. (C) 1998 Elsevier Science B.V.

引用

页码：138 / 142

页数：5

共 26 条

[1] ULTRAFAST INFRARED-SPECTROSCOPY OF VIBRATIONAL CO-STRETCH UP-PUMPING AND RELAXATION DYNAMICS OF W(CO)(6) [J].

ARRIVO, SM ;

DOUGHERTY, TP ;

GRUBBS, WT ;

HEILWEIL, EJ .

CHEMICAL PHYSICS LETTERS, 1995, 235 (3-4) :247-254

[2] POLARITON EFFECTS IN 4-WAVE-MIXING [J].

BAKKER, HJ ;

KURZ, H .

PHYSICAL REVIEW B, 1994, 50 (11) :7805-7808

[3] ULTRAFAST INFRARED SATURATION SPECTROSCOPY OF CHLOROFORM, BROMOFORM, AND IODOFORM [J].

BAKKER, HJ ;

PLANKEN, PCM ;

KUIPERS, L ;

LAGENDIJK, A .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (03) :1730-1739

[4] NUMERICAL-CALCULATION OF OPTICAL FREQUENCY-CONVERSION PROCESSES - A NEW APPROACH [J].

BAKKER, HJ ;

PLANKEN, PCM ;

MULLER, HG .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (09) :1665-1672

[5] SELF-CONSISTENT THEORY OF TIME-RESOLVED 4-WAVE-MIXING [J].

BELOV, MN ;

MANYKIN, EA ;

SELIFANOV, MA .

OPTICS COMMUNICATIONS, 1993, 99 (1-2) :101-104

[6] Vibrational dephasing mechanisms in hydrogen-bonded systems [J].

Bonn, M ;

Brugmans, MJP ;

Kleyn, AW ;

vanSanten, RA ;

Bakker, HJ .

PHYSICAL REVIEW LETTERS, 1996, 76 (14) :2440-2443

[7] FREE-ELECTRON LASER AS A TOOL FOR PUMP-PROBE MEASUREMENTS OF THE VIBRATIONAL-RELAXATION IN CONDENSED PHASES [J].

BROQUIER, M ;

DUBOST, H ;

KOLOS, R ;

LEFEVRE, J ;

TRAMER, A ;

BERSET, JM ;

ORTEGA, JM ;

PEREMANS, A .

OPTICS COMMUNICATIONS, 1995, 118 (3-4) :255-260

[8] PROPAGATION OF SMALL-AREA PULSES OF COHERENT LIGHT THROUGH A RESONANT MEDIUM [J].

CRISP, MD .

PHYSICAL REVIEW A, 1970, 1 (06) :1604-&

[9] COHERENT PROPAGATION AND QUANTUM BEATS OF QUADRUPOLE POLARITONS IN CU2O [J].

FROHLICH, D ;

KULIK, A ;

UEBBING, B ;

MYSYROWICZ, A ;

LANGER, V ;

STOLZ, H ;

VONDEROSTEN, W .

PHYSICAL REVIEW LETTERS, 1991, 67 (17) :2343-2346

[10] COHERENT TRANSIENTS OF PUMP-PROBE SPECTROSCOPY IN 2-LEVEL APPROXIMATION [J].

GAIZAUSKAS, E ;

VALKUNAS, L .

OPTICS COMMUNICATIONS, 1994, 109 (1-2) :75-80

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