Novel 2D supramolecular array based on antibacterial drug norfloxacin

被引：21

作者：

Wang, YC

Hong, Z

Qiong, Y

Chen, ZF

Xiong, RG ^{[2
]}

Fun, HK

机构：

[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

[2] Nanjing Univ, Inst Coordinat Chem, State Lab Coordinat Chem, Nanjing 210093, Peoples R China

[3] Xuzhou Normal Univ, Dept Chem, Xuzhou 221116, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 14期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

cadmium; norfloxacin; self-assembly; metal-organic framework; fluorescence;

D O I：

10.1016/j.ica.2004.05.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly reaction of Cd(CIO4)(2)(.)6H(2)O with Norfloxacin (H-Norf) affords a novel 2D rectangular grid framework [Cd(Norf)(ClO4)(H2O)] (1) with strong blue luminescent emission (lambda(cm) = 425 nm), while Norf(-) acts as a tetradentate bridging linker to connect three Cd centers and ClO4- completes Cd center octahedron coordination geometry. The compound 1 has crystallographic data of triclinic, space group P (1) over bar, a = 9.4577(1) Angstrom, b = 9.5012(2) Angstrom, c = 12.2805(1) Angstrom, V = 3624.4(3) Angstrom(3), Z = 2. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4303 / 4308

页数：6

共 49 条

[1] CRYSTAL-STRUCTURE OF 2-SULFANILAMIDOPYRIMIDINESILVER(I) [J].