Spontaneous transformation of selenium from monoclinic micro-balls to trigonal nano-rods in ethanol solution

被引：14

作者：

Xie, SY ^{[1
]}

Wang, CF ^{[1
]}

Zhang, XH ^{[1
]}

Jiang, ZY ^{[1
]}

Xie, ZX ^{[1
]}

Tian, ZQ ^{[1
]}

Huang, RB ^{[1
]}

Zheng, LS ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2003年 / 13卷 / 06期

关键词：

D O I：

10.1039/b300524k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In a solution of ethanol, Se micro-balls produced in the glow discharge of H2Se, comprising a mixture of trigonal and monoclinic phases, spontaneously converted to nano-rods with diameters of ca. 30-180 nm and lengths up to 1 mum. This solid-liquid-solid process, with high yield and low cost, may be extended to the manufacture of one-dimensional nano-materials from allotropes several hundred times larger than the nano-materials formed.

引用

页码：1447 / 1450

页数：4

共 22 条

[1] MORPHOLOGY OF SPHERULITES AND SINGLE CRYSTALS OF TRIGONAL SELENIUM [J].

FITTON, B ;

GRIFFITH.CH .

JOURNAL OF APPLIED PHYSICS, 1968, 39 (08) :3663-&

[2]

Gates B, 2002, ADV FUNCT MATER, V12, P219, DOI 10.1002/1616-3028(200203)12:3<219::AID-ADFM219>3.0.CO

[3]

2-U

[4] A solution-phase approach to the synthesis of uniform nanowires of crystalline selenium with lateral dimensions in the range of 10-30 nm [J].

Gates, B ;

Yin, YD ;

Xia, YN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (50) :12582-12583

[5] Selenium nanoparticles: A small-angle neutron scattering study [J].

Johnson, JA ;

Saboungi, ML ;

Thiyagarajan, P ;

Csencsits, R ;

Meisel, D .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (01) :59-63

[6] EFFECT OF PARTICLE-SIZE ON STABILITY OF MONODISPERSE SELENIUM HYDROSOLS [J].

JOSEPHPETIT, AM ;

DUMONT, F ;

WATILLON, A .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1973, 43 (03) :649-661

[7] Nanolithography based on patterned metal transfer and its application to organic electronic devices [J].

Kim, C ;

Shtein, M ;

Forrest, SR .

APPLIED PHYSICS LETTERS, 2002, 80 (21) :4051-4053

[8] Protein nanoarrays generated by dip-pen nanolithography [J].

Lee, KB ;

Park, SJ ;

Mirkin, CA ;

Smith, JC ;

Mrksich, M .

SCIENCE, 2002, 295 (5560) :1702-1705

[9] Pressure induced structural transitions in nanocrystalline grained selenium [J].

Liu, HZ ;

Jin, CQ ;

Zhao, YH .

PHYSICA B-CONDENSED MATTER, 2002, 315 (1-3) :210-214

[10] IDENTIFICATION OF FUNDAMENTAL VIBRATIONAL MODES OF TRIGONAL ALPHA-MONOCLINIC AND AMORPHOUS SELENIUM [J].

LUCOVSKY, G ;

MOORADIAN, A ;

TAYLOR, W ;

WRIGHT, GB ;

KEEZER, RC .

SOLID STATE COMMUNICATIONS, 1967, 5 (02) :113-+

← 1 2 3 →