Simple primary anilines as iminium catalysts for the epoxidation of α-substituted acroleins

被引：27

作者：

Erkkila, Anniina

Pihko, Petri M.

Clarke, Melanie-Rose

机构：

[1] Laboratory of Organic Chemistry, Department of Chemical Technology, FI-02015 TKK

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 06期

关键词：

anilines; epoxides; iminium catalysis; organocatalysis;

D O I：

10.1002/adsc.200700048

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Simple ortho-alkylated anilines have been shown to be excellent iminium catalysts for the epoxidation reaction of alpha-substituted acroleins. A range of different alpha-substituted acroleins give the epoxide products in good to excellent yields and good chemoselectivity.

引用

收藏

页码：802 / 806

页数：5

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