A highly luminescent europium complex showing visible-light-sensitized red emission: Direct observation of the singlet pathway

被引：357

作者：

Yang, C

Fu, LM

Wang, Y ^{[1
]}

Zhang, JP

Wong, WT

Ai, XC

Qiao, YF

Zou, BS

Gui, LL

机构：

[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China

[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[4] Guangdong Univ Technol, Fac Chem Engn & Light Ind, Guangzhou 510090, Peoples R China

[5] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China

[6] Guangdong Univ Technol, Fac Chem Engn & Light Ind, Guangzhou 510090, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 38期

关键词：

energy-transfer mechanisms; europium; luminescence; sensitizers; time-resolved spectroscopy;

D O I：

10.1002/anie.200454141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Red glow in daylight ... chemist's delight! An efficient transfer of excitation energy from the ligand to the luminescent states of the coordinated EuIII ion in 1 occurs from the singlet excited state of the ligand. The complex shows characteristic bright red Eu-centered emission with a quantum yield of 0.52 when sensitized with visible light.

引用

页码：5010 / 5013

页数：4

共 18 条

[1]

ADABHOY A, 2000, J CHEM SOC P2, P2359

[2] NONPARTICIPATION OF THE LIGANDS FIRST TRIPLET-STATE IN INTRAMOLECULAR ENERGY-TRANSFER IN EU3+ AND TB3+ RUHEMANNS PURPLE COMPLEXES [J].

ALAOUI, IM .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (35) :13280-13282

[3] The efficient intramolecular sensitisation of terbium(III) and europium(III) by benzophenone-containing ligands [J].

Beeby, A ;

Bushby, LM ;

Maffeo, D ;

Williams, JAG .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (07) :1281-1283

[4] Site-isolated luminescent europium complexes with polyester macroligands: Metal-centered heteroarm stars and nanoscale assemblies with labile block junctions [J].

Bender, JL ;

Corbin, PS ;

Fraser, CL ;

Metcalf, DH ;

Richardson, FS ;

Thomas, EL ;

Urbas, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) :8526-8527

[5] Ratiometric probes for hydrogencarbonate analysis in intracellular or extracellular environments using europium luminescence [J].

Bretonnière, Y ;

Cann, MJ ;

Parker, D ;

Slater, R .

CHEMICAL COMMUNICATIONS, 2002, (17) :1930-1931

[6] EUROPIUM(III) LUMINESCENCE AND TYROSINE TO TERBIUM(III) ENERGY-TRANSFER STUDIES OF INVERTEBRATE (OCTOPUS) CALMODULIN [J].

BRUNO, J ;

HORROCKS, WD ;

ZAUHAR, RJ .

BIOCHEMISTRY, 1992, 31 (31) :7016-7026

[7] Spectroscopic properties and design of highly luminescent lanthanide coordination complexes [J].

de Sá, GF ;

Malta, OL ;

Donegá, CD ;

Simas, AM ;

Longo, RL ;

Santa-Cruz, PA ;

da Silva, EF .

COORDINATION CHEMISTRY REVIEWS, 2000, 196 :165-195

[8] LANTHANIDE ION LUMINESCENCE PROBES - MEASUREMENT OF DISTANCE BETWEEN INTRINSIC PROTEIN FLUOROPHORES AND BOUND METAL-IONS - QUANTITATION OF ENERGY-TRANSFER BETWEEN TRYPTOPHAN AND TERBIUM(III) OR EUROPIUM(III) IN THE CALCIUM-BINDING PROTEIN PARVALBUMIN [J].

DEHORROCKS, W ;

COLLIER, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (10) :2856-2862

[9]

DEMAS JN, 1971, J PHYS CHEM-US, V75, P991, DOI 10.1021/j100678a001

[10] LASER-DYE DCM, ITS SPECTRAL PROPERTIES, SYNTHESIS AND COMPARISON WITH OTHER DYES IN THE RED [J].

HAMMOND, PR .

OPTICS COMMUNICATIONS, 1979, 29 (03) :331-333

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