FeCl3: Highly Efficient Catalyst for Synthesis of α-Amino Nitriles

被引：13

作者：

Heravi, Majid M. ^{[1
]}

Ebrahimzadeh, Mojgan ^{[1
]}

Oskooie, Hossein A. ^{[1
]}

Baghernejad, Bita ^{[1
]}

机构：

[1] Alzahra Univ, Sch Sci, Dept Chem, Tehran, Iran

来源：

CHINESE JOURNAL OF CHEMISTRY | 2010年 / 28卷 / 03期

关键词：

one-pot; FeCl3; trimethyl silyl cyanide; alpha-aminonitriles; ONE-POT SYNTHESIS; GREEN; ACID;

D O I：

10.1002/cjoc.201090100

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha-Amino nitriles are synthesized by the three-component coupling reaction of aldehydes, amines and trimethyl-silyl cyanide using FeCl3 as a solid acid catalyst, under solvent-free conditions in good yields. The catalyst was recovered by simple filtration and was recycled in subsequent reactions.

引用

收藏

页码：480 / 482

页数：3

相关论文

共 31 条

[1] Catalytic method for synthesis of aspirin by a green, efficient and recyclable solid acid catalyst (Preyssler's anion) at room temperature [J].

Bamoharram, Fatemeh F. ;

Heravi, Majid M. ;

Roshani, Mina ;

Gharib, Ali ;

Jahangir, Manouchehr .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2007, 54 (04) :1017-1020

[2] Preyssler catalyst,[NaP5W30O110]14- :: A green, efficient and reusable catalyst for esterification of salicylic acid with aliphatic and benzylic alcohols [J].

Bamoharram, FF ;

Heravi, MM ;

Roshani, M ;

Jahangir, M ;

Gharib, A .

APPLIED CATALYSIS A-GENERAL, 2006, 302 (01) :42-47

[3] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[4] DIASTEREOSELECTIVE STRECKER SYNTHESIS USING ALPHA-PHENYLGLYCINOL AS CHIRAL AUXILIARY [J].

CHAKRABORTY, TK ;

REDDY, GV ;

HUSSAIN, KA .

TETRAHEDRON LETTERS, 1991, 32 (51) :7597-7600

[5] Vanadyl triflate as an efficient and recyclable catalyst for trimethylsilyl cyanide addition to carbonyl compounds [J].

De, SK ;

Gibbs, RA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 232 (1-2) :123-125

[6] Bismuth trichloride catalyzed synthesis of α-aminonitriles [J].

De, SK ;

Gibbs, RA .

TETRAHEDRON LETTERS, 2004, 45 (40) :7407-+

[7] Recent uses of iron (III) chloride in organic synthesis [J].

Díaz, DD ;

Miranda, PO ;

Padrón, JI ;

Martín, VS .

CURRENT ORGANIC CHEMISTRY, 2006, 10 (04) :457-476

[8] RECENT DEVELOPMENTS IN THE STEREOSELECTIVE SYNTHESIS OF ALPHA-AMINO-ACIDS [J].

DUTHALER, RO .

TETRAHEDRON, 1994, 50 (06) :1539-1650

[9] Some recent applications of α-amino nitrile chemistry [J].

Enders, D ;

Shilvock, JP .

CHEMICAL SOCIETY REVIEWS, 2000, 29 (05) :359-373

[10] Advances in iron catalyzed cross coupling reactions [J].

Fürstner, A ;

Martin, R .

CHEMISTRY LETTERS, 2005, 34 (05) :624-629

← 1 2 3 4 →