Polarization switching in (001)-oriented Pb(Mg1/3Nb2/3)O3-x%PbTiO3 crystals:: Direct observation of heterogeneous nucleation by piezoreponse force microscopy

被引:11
作者
Bai, FM [1 ]
Li, JF [1 ]
Viehland, D [1 ]
机构
[1] Virginia Tech, Dept Mat Sci & Engn, Blacksburg, VA 24061 USA
关键词
D O I
10.1063/1.1819993
中图分类号
O59 [应用物理学];
学科分类号
摘要
Polarization switching in (001)-oriented Pb(Mg1/3Nb2/3)O-3-x%PbTiO3, PMN-x%PT, crystals for x=20 and 35 has been investigated in situ by scanning force microscopy in a piezoresponse mode, under a step-increased dc electrical voltage (V-dc). The results demonstrate that switching initiates by the nucleation of nanosized polar regions with a reversed polarization. For x=20, nucleation occurs heterogeneously throughout the volume of the crystal. However, with increasing PT content, nucleation tends to preferentially initiate near preexisting twin boundaries; with increasing V-dc, the domains becoming increasingly "diffuse" due to heterogeneous nucleation and growth throughout the crystal. (C) 2004 American Institute of Physics.
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页码:4457 / 4459
页数:3
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