Brucine and two solvates

被引:26
作者
Bialonska, A [1 ]
Ciunik, Z [1 ]
机构
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷
关键词
D O I
10.1107/S0108270104024874
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures of brucine ( 2,3- dimethoxystrychnidin-10- one), C23H26N2O4, brucine acetone solvate, C23H26N2O4 . C3H6O, and brucine 2- propanol solvate dihydrate, C23H26N2O4 . C3H7O .2H(2)O, have been determined. Crystals of brucine and its 2- propanol solvate dihydrate exhibit similar monolayer sheet packing, whereas crystals of the acetone solvate adopt a different mode of packing, as brucine pillars. The solvent appears to control the brucine self- assembly on the basis of common donor - acceptor properties of the surfaces.
引用
收藏
页码:O853 / O855
页数:3
相关论文
共 13 条
[11]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
[12]   PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].
SHELDRICK, GM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473
[13]  
Tanaka K, 2001, HETEROCYCLES, V54, P405