共 22 条
Solubility of oxygen in liquid perfluorocarbons
被引:94
作者:
Dias, AMA
[1
]
Freire, M
[1
]
Coutinho, JAP
[1
]
Marrucho, IM
[1
]
机构:
[1] Univ Aveiro, Dept Chem, CICECO, P-3810193 Aveiro, Portugal
关键词:
solubility measurements;
oxygen;
perfluorocarbons;
D O I:
10.1016/j.fluid.2004.06.037
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
The solubility of oxygen in several liquid perfluorocarbons was measured in the temperature range between 288 and 313 K and at pressures close to atmospheric. Values were measured with an apparatus based on the saturation method with an accuracy of +/-1%. Thermodynamic functions such as Gibbs energy, enthalpy and entropy of solution were obtained from the composition and temperature dependence. The Peng-Robinson equation of state was used to model the gas solubility for the studied systems. (C) 2004 Elsevier B.V. All rights reserved.
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页码:325 / 330
页数:6
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