Fluidic Carbon Precursors for Formation of Functional Carbon under Ambient Pressure Based on Ionic Liquids

被引:326
作者
Lee, Je Seung [1 ]
Wang, Xiqing [1 ]
Luo, Huimin [2 ]
Dai, Sheng [1 ]
机构
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[2] Oak Ridge Natl Lab, Nucl Sci & Technol Div, Oak Ridge, TN 37831 USA
关键词
ORDERED MESOPOROUS CARBON; OXYGEN REDUCTION REACTION; IONOTHERMAL SYNTHESIS; FUEL-CELLS; CATALYSTS; NANOPARTICLES; PERFORMANCE; STORAGE; IMIDAZOLIUM; FABRICATION;
D O I
10.1002/adma.200903403
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new strategy for the preparation of functional porous carbons is developed via direct, ambient-pressure, thermal pyrolysis of task-specific ionic liquids (ILs). The simple synthesis lies in the synergistic use of the negligible volatility of the ILs and incorporation of the crosslinkable nitrile groups in the anions. The resulting carbon materials at 800 degrees C retain an extremely high content of nitrogen (up to 18 at%).
引用
收藏
页码:1004 / +
页数:5
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