A facile and novel way for the synthesis of nearly monodisperse silver nanoparticles

被引:56
作者
Chen, Zhitao [1 ]
Gao, Lian [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
关键词
metals; nanostructure; chemical synthesis; electron microscopy; optical properties;
D O I
10.1016/j.materresbull.2006.11.028
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A facile and novel way was reported for the preparation of nearly monodisperse silver nanoparticles with controlled hydrophilic or hydrophobic surface, using trioctylphosphine as the surfactant and stabilizer. The synthesized nanoparticles were characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and UV-vis spectroscopy. The monodisperse silver nanoparticles showed a strong surface plasmon resonance band at 402 nm from the UV-vis spectrum. (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1657 / 1661
页数:5
相关论文
共 29 条
[1]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[2]   Synthesis of coinage-metal nanoparticles from mesityl precursors [J].
Bunge, SD ;
Boyle, TJ ;
Headley, TJ .
NANO LETTERS, 2003, 3 (07) :901-905
[3]   Mercaptoammonium-monolayer-protected, water-soluble gold, silver, and palladium clusters [J].
Cliffel, DE ;
Zamborini, FP ;
Gross, SM ;
Murray, RW .
LANGMUIR, 2000, 16 (25) :9699-9702
[4]   Recent advances in the liquid-phase syntheses of inorganic nanoparticles [J].
Cushing, BL ;
Kolesnichenko, VL ;
O'Connor, CJ .
CHEMICAL REVIEWS, 2004, 104 (09) :3893-3946
[5]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[6]  
FARADAY M, 1857, PHILOS T ROY SOC LON, V147, P145, DOI [10.1098/rstl.1857.0011, DOI 10.1098/RSTL.1857.0011]
[7]   Is the anion the major parameter in the shape control of nanocrystals? [J].
Filankembo, A ;
Giorgio, S ;
Lisiecki, I ;
Pileni, MP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (30) :7492-7500
[8]   Trialkylphosphine oxide/amine stabilised silver nanocrystals - the importance of steric factors and Lewis basicity in capping agents [J].
Green, M ;
Allsop, N ;
Wakefield, G ;
Dobson, PJ ;
Hutchison, JL .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (09) :2671-2674
[9]   A simple one phase preparation of organically capped gold nanocrystals [J].
Green, M ;
O'Brien, P .
CHEMICAL COMMUNICATIONS, 2000, (03) :183-184
[10]   A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants [J].
Hiramatsu, H ;
Osterloh, FE .
CHEMISTRY OF MATERIALS, 2004, 16 (13) :2509-2511