Synthesis and properties of novel poly(p, phenylenevinylene)s containing a tricarbonyl(arene)chromium unit in the main chain

被引：15

作者：

Morisaki, Y ^{[1
]}

Chen, H ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

POLYMER BULLETIN | 2003年 / 50卷 / 1-2期

关键词：

D O I：

10.1007/s00289-003-0131-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Novel pi-conjugated polymers based. on poly-(p-phenylenevinylene)s (PPVs) containing a tricarbonyl(arene)chromium unit in the main chain were synthesized by Horner-Wadsworth-Emmons olefination. The structures of the polymers were supported by H-1 NMR and IR spectra. The polymers obtained were soluble in common solvents such as THF, CH2Cl2, CHCl3 and toluene. The molecular weights of the polymers were determined by GPC. Their thermal, optical, and electrochemical properties were investigated in detail.

引用

页码：39 / 46

页数：8

共 34 条

[1] Polymerization of methacrylates containing cationic cyclopentadienyliron moieties [J].

Abd-El-Aziz, AS ;

Todd, EK ;

Ma, GZ ;

DiMartino, J .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, 2000, 10 (04) :265-272

[2] Synthesis and characterization of novel organoiron polymers [J].

Abd-El-Aziz, AS ;

Todd, EK ;

Epp, KM .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, 1998, 8 (02) :127-133

[3] Design of polyaromatic ethers using cyclopentadienyliron complexes [J].

Abd-El-Aziz, AS ;

de Denus, CR ;

Todd, EK ;

Bernardin, SA .

MACROMOLECULES, 2000, 33 (14) :5000-5005

[4]

ABDELAZIZ AS, 1999, POLYM PREPR AM CHEM, V40, P926

[5] 3RD-ORDER NONLINEAR-OPTICAL RESPONSE IN ORGANIC MATERIALS - THEORETICAL AND EXPERIMENTAL ASPECTS [J].

BREDAS, JL ;

ADANT, C ;

TACKX, P ;

PERSOONS, A ;

PIERCE, BM .

CHEMICAL REVIEWS, 1994, 94 (01) :243-278

[6]

COLLMAN P, 1987, PRINCIPLES APPL ORGA

[7] Synthesis of oligomeric and polymeric ethers containing the Cp*Ru+ and CpFe+ metal moieties [J].

de Denus, CR ;

Hoffa, LM ;

Todd, EK ;

Abd-El-Aziz, AS .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, 2000, 10 (04) :189-208

[8]

Dembek A. A., 1994, POLYM MATER SCI ENG, V71, P158

[9] ORGANOMETALLIC MODIFICATION APPROACH TO CONTROL OF POLYMER PROPERTIES - A SOLUBLE, LIQUID-CRYSTALLINE, PI-COMPLEXED AROMATIC POLYAMIDE [J].

DEMBEK, AA ;

BURCH, RR ;

FEIRING, AE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :2087-2089

[10]

DEMBEK AA, 1993, MACROMOLECULES, V26, P2292

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