Distinct Catalytic Effect of Micellar Solution of Sodium Dodecyl Sulfate (SDS) for One-Pot Conversion of Alkyl Halides to Disulfides via an Odourless Process Using Thiourea and MnO2

被引：17

作者：

Firouzabadi, Habib ^{[1
]}

Iranpoor, Nasser ^{[1
]}

Abbasi, Mohammad ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2010年 / 83卷 / 06期

关键词：

PHASE-TRANSFER CONDITIONS; APROTIC ORGANIC-SOLVENTS; MICHAEL ADDITION; DIALKYL DISULFIDES; BOND FORMATION; SYMMETRICAL DISULFIDES; CONVENIENT SYNTHESIS; EFFICIENT SYNTHESIS; BARIUM MANGANATE; ZN/ALCL3; SYSTEM;

D O I：

10.1246/bcsj.20090333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel one-pot odourless synthesis of symmetrical disulfides from their corresponding halides in aqueous media using thiourea and MnO2 in the presence of NaHCO3 or Na2CO3 catalyzed by micellar solution of sodium dodecyl sulfate (SDS) is described. By this method, primary, allylic and benzylic halides were converted into their corresponding disulfides in high yields.

引用

页码：698 / 702

页数：5

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