Self-assembly of block copolymers in thin films

被引:101
作者
Matsen, MW [1 ]
机构
[1] Univ Reading, Ctr Polymer Sci, Reading RG6 6AF, Berks, England
关键词
D O I
10.1016/S1359-0294(98)80040-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Block copolymers are recognized for their tendency to form well-ordered periodic microstructures, often with exceptionally intricate geometries. This class of molecule now promises to provide important commercial applications in the form of thin films. There have been many recent advances in the effort to create confined films, control surface potentials, probe and manipulate morphology, explain equilibrium behaviour, and understand kinetics. Such advances will be crucial in the development of applications for block copolymer films such as surface coatings, porous membranes, waveguides, and nanoscale templates.
引用
收藏
页码:40 / 47
页数:8
相关论文
共 66 条
[1]   Thermal annealing of roll-cast triblock copolymer films [J].
Albalak, RJ ;
Thomas, EL ;
Capel, MS .
POLYMER, 1997, 38 (15) :3819-3825
[2]   ALIGNMENT OF LAMELLAR BLOCK-COPOLYMER MICROSTRUCTURE IN AN ELECTRIC-FIELD .2. MECHANISMS OF ALIGNMENT [J].
AMUNDSON, K ;
HELFAND, E ;
QUAN, XN ;
HUDSON, SD ;
SMITH, SD .
MACROMOLECULES, 1994, 27 (22) :6559-6570
[3]   ALIGNMENT OF LAMELLAR BLOCK-COPOLYMER MICROSTRUCTURE IN AN ELECTRIC-FIELD .1. ALIGNMENT KINETICS [J].
AMUNDSON, K ;
HELFAND, E ;
QUAN, X ;
SMITH, SD .
MACROMOLECULES, 1993, 26 (11) :2698-2703
[4]   THE MORPHOLOGY OF SYMMETRIC DIBLOCK COPOLYMERS AS REVEALED BY NEUTRON REFLECTIVITY [J].
ANASTASIADIS, SH ;
RUSSELL, TP ;
SATIJA, SK ;
MAJKRZAK, CF .
JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (09) :5677-5691
[5]   FLUCTUATIONS, CONFORMATIONAL ASYMMETRY AND BLOCK-COPOLYMER PHASE-BEHAVIOR [J].
BATES, FS ;
SCHULZ, MF ;
KHANDPUR, AK ;
FORSTER, S ;
ROSEDALE, JH ;
ALMDAL, K ;
MORTENSEN, K .
FARADAY DISCUSSIONS, 1994, 98 :7-18
[6]   USING PARAMETRIC B-SPLINES TO FIT SPECULAR REFLECTIVITIES [J].
BERK, NF ;
MAJKRZAK, CF .
PHYSICAL REVIEW B, 1995, 51 (17) :11296-11309
[7]  
Binder K, 1997, J PHYS II, V7, P1353, DOI 10.1051/jp2:1997191
[8]  
BINDER K, 1997, IN PRESS ADV POLYM S
[9]   THEORETICAL PREDICTION OF THE OPTICAL WAVE-GUIDING PROPERTIES OF SELF-ASSEMBLED BLOCK-COPOLYMER FILMS [J].
CHEN, JT ;
THOMAS, EL ;
ZIMBA, CG ;
RABOLT, JF .
MACROMOLECULES, 1995, 28 (17) :5811-5818
[10]   Observed substrate topography-mediated lateral patterning of diblock copolymer films [J].
Fasolka, MJ ;
Harris, DJ ;
Mayes, AM ;
Yoon, M ;
Mochrie, SGJ .
PHYSICAL REVIEW LETTERS, 1997, 79 (16) :3018-3021