A new soluble 1,10-phenanthroline-containing π-conjugated polymer:: Synthesis and effect of metal complexation on optical properties

被引：99

作者：

Yasuda, T ^{[1
]}

Yamaguchi, I ^{[1
]}

Yamamoto, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, 4259 Nagatsuta, Yokohama, Kanagawa 2268503, Japan

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 04期

关键词：

D O I：

10.1002/adma.200390070

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The π-Conjugated polymers containing the metal complexes of phen and bpy were said to be promising functional materials. However, the metal complex forming reactivity of these polymers and the optical properties of their metal complexes were not extensively analyzed, especially for non-substituted pphen, due to its poor solubility in organic solvents. Recently, soluble arylene ethynylene type π-conjugated polymers consisting of the phen unit and related low molecular compounds were synthesized, and their highly luminescent properties in solutions were revealed. This paper reports the preparation of a new, soluble phen-containing π-conjugated polymer 1 and its low molecular model compound 2, and their optical properties tuned by metal complexation.

引用

页码：293 / 296

页数：4

共 36 条

[31] POLYPYRIDINE BLOCK AS MOLECULAR ANTENNA IN PHOTOLUMINESCENCE OF MACROMOLECULAR SYSTEMS [J].